MORPHOLOGY AND DIMENSION VARIATIONS OF COPPER SULFIDE FOR HIGH PERFORMANCE ELECTRODE IN RECHARGEABLE BATTERIES: A REV
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Date
2020
Authors
Kalimuldina, Gulnur
Nurpeissova, Arailym
Adylkhanova, Assyl
Adair, Desmond
Taniguchi, Izumi
Bakenov, Zhumabay
Journal Title
Journal ISSN
Volume Title
Publisher
ACS Applied Energy Materials
Abstract
Currently, different metal sulfides (NiS, Co9S8, FeS2, and CuS) have been extensively studied as alternative electrodes
for rechargeable batteries that can satisfy the performance requirements for more powerful energy supply and storage technologies
for various applications and industries. Among them, copper sulfides have gained significant attention as a promising electrode
material in rechargeable metal-ion (Li, Mg, Na, and Al) batteries. A wide range of synthesis routes and methods have been
implemented in order to prepare various stoichiometry CuxS (1 ≤ x ≤ 2) micro-/nanostructured materials with excellent
electrochemical properties. Since the bulk microsized electrode materials have almost reached their performance limits for energy
devices, the introduction of nanoscale CuxS composites is now in high demand. This review focuses on the influence of the material
morphology and dimensions on their performance in secondary batteries. The structures of CuxS materials from zero-dimensional
(0D) to 3D and their preparation are discussed. The primary purpose of this work is to provide an overview of the unique
electrochemical and physical properties of particular structure and dimensionality which can promote these materials’ application in
the energy storage field. Along with this, this work summarizes the information on various synthesis strategies and how they can
manage the morphologies of CuxS micro-/nanocomposites. In the current fast technologically advancing society, the development of
the most economically profitable and efficient synthesis routes is especially encouraged and required, and this aspect is also
commented on in this review
Description
Keywords
Type of access: Open Access, copper sulfide, dimensionality, 0D copper sulfide, 1D copper sulfide, 2D copper sulfide, 3D copper sulfide, lithium-ion battery, metal sulfide
Citation
Kalimuldina, G., Nurpeissova, A., Adylkhanova, A., Adair, D., Taniguchi, I., & Bakenov, Z. (2020). Morphology and Dimension Variations of Copper Sulfide for High-Performance Electrode in Rechargeable Batteries: A Review. ACS Applied Energy Materials, 3(12), 11480–11499. https://doi.org/10.1021/acsaem.0c01686