Synthesis of trans-porphyrin dimers for nonlinear optics

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dc.contributor.authorBaptayev, Bakhytzhan
dc.contributor.authorTauanov, Zhandos
dc.contributor.authorBissengaliyeva, Moldir
dc.contributor.authorZhakiyeva, Zhanar
dc.contributor.authorBerillo, Dmitriy
dc.contributor.authorAdilov, Salimgerey
dc.date.accessioned2016-03-02T06:01:39Z
dc.date.available2016-03-02T06:01:39Z
dc.date.issued2014
dc.description.abstractFollowing the development of the idea of octupolar molecules as nonlinear optical materials a variety of compounds have been reported. Trans-porphyrins have a great potential to self-order into octupolar symmetry. Nonlinear optical properties can be tuned by using strong donor-acceptor groups in porphyrins as well as extention of conjugation. Here we report the syntheses of trans-A2D2-porphyrins and their dimerization into cubic octupoles by lanthanides and organic bidentate ligands. Bulky groups are employed to induce non-centrosymmetric eclipsed or staggered conformations. Effect of donor acceptor groups, dimerization conditions and crystal packing of dimers are studied.ru_RU
dc.description.sponsorshipResearch Grant of Ministry of Education and Science of Kazakhstanru_RU
dc.identifier.urihttp://nur.nu.edu.kz/handle/123456789/1336
dc.language.isoenru_RU
dc.publisher“NURIS”, Nazarbayev University, Astana, Kazakhstanru_RU
dc.rightsAttribution-NonCommercial-ShareAlike 3.0 United States*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-sa/3.0/us/*
dc.subjectsynthesis of trans-porphyrin dimersru_RU
dc.subjectsynthesis of trans-porphyrinsru_RU
dc.subjectcrystal structure of dimersru_RU
dc.subjectdimerization with bidentate ligandsru_RU
dc.subjectResearch Subject Categories::MEDICINE::Microbiology, immunology, infectious diseasesru_RU
dc.titleSynthesis of trans-porphyrin dimers for nonlinear opticsru_RU
dc.typeOtherru_RU

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